Macroporous alumina microspheres

Macroporous alumina microspheres

Catalyst Carrier
Alumina microspheres are an innovative catalyst support, distinguished by their fine particle size and expansive specific surface area, facilitating rapid surface catalytic reactions. Their porous structure also enables effortless impregnation and loading with elements like rare earth metals, resulting in a highly active catalys

Product Description

Macroporous Alumina Microspheres | Catalyst Support & Adsorbent
Macroporous · High-Flow      Spherical Alumina · Optimized Pore Network

Macroporous Alumina Microspheres 

Engineered spherical alumina microspheres with interconnected macroporosity (pore diameters > 50 nm) and high surface area. Designed for demanding catalyst support, high-flow adsorption, and heavy-metal removal applications where rapid mass transfer and low pressure drop are critical.

Morphology
Spherical Beads (0.2 – 3 mm)
BET Surface Area
180 – 280 m²/g
Macropore Volume
≥ 0.45 mL/g
Crush Strength
≥ 35 N (avg.)

Spherical Geometry & Internal Architecture

Bimodal pore structure combines macroporous transport channels with mesoporous active sites.

Macroporous alumina microspheres

Figure 1: Cross-section of macroporous alumina microsphere (interconnected pore network)
Controlled Macro-Meso Porosity              0.2 – 3.0 mm
Spherical shape ensures uniform packing density, while tailored macropores (50–200 nm) facilitate rapid molecular diffusion, reducing internal mass-transfer limitations in liquid-phase reactions.
High Mechanical Integrity              ≥ 35 N/bead
Optimized binder system and sintering profile yield strong, attrition-resistant spheres suitable for fixed-bed and moving-bed reactors with low fines generation.

Key Application Fields

From petrochemical catalysis to advanced water treatment — macroporous microspheres excel.

Refining & Petrochem

Hydrotreating & Resid Upgrading

Used as catalyst support for heavy oil hydroprocessing, where large molecules require accessible pore architectures and stable alumina matrix.

  • High metal (Ni, Mo, Co) loading capacity
  • Resists fouling from asphaltenes
  • Extended cycle length
Adsorption / Separation

Selective Adsorption & Ion Exchange

Ideal for removal of fluoride, arsenic, and heavy metals from aqueous streams, as well as drying and purification of organic solvents.

  • Fast adsorption kinetics
  • High capacity for anions/cations
  • Regenerable with mild elution
Environmental & Chemical

Scrubbing & Catalytic Oxidation

Deployed in VOC abatement, ozone decomposition, and selective catalytic reduction (SCR) units as a robust, thermally stable support.

  • Thermal stability up to 1200 °C
  • Resists acid/basic gas attack
  • Low pressure drop in packed beds

Technical Specifications (TDS)

Standard physical and chemical property benchmarks for macroporous alumina microspheres.

Technical PropertyStandard Specification RangeCustomization Options
Crystal PhaseGamma / Theta / MixedHigh-purity Alpha or tailored phase
Particle Size (mm)0.2–0.5, 0.5–1.0, 1.0–2.0, 2.0–3.0Custom cuts (e.g., 0.3–0.6 mm)
BET Surface Area (m²/g)180 – 280Low/high surface area variants
Total Pore Volume (mL/g)0.65 – 0.95Optimized for specific diffusion needs
Macropore Volume (>50 nm)≥ 0.45 mL/gControlled macro/meso ratio
Crush Strength (N/bead, avg.)≥ 35 (size dependent)High-strength formulations available
Al₂O₃ Purity (wt%)≥ 98.5 %Low Na₂O, low SiO₂ grades
Bulk Density (g/mL)0.55 – 0.80Calibrated for reactor loading

Engineered Performance Advantages

Designed for process intensification and long-term reliability.

1. Rapid Mass Transfer

Interconnected macropores act as high-speed highways for reactants, while mesopores provide abundant active sites — eliminating diffusion barriers.

2. Superior Flow Distribution

Spherical morphology ensures even liquid/gas distribution, minimizing channeling and maximizing utilization of the entire bed volume.

3. High Attrition Resistance

Robust sphere integrity reduces dust formation during handling and operation, improving reactor hygiene and reducing downstream fouling.

4. Chemical Versatility

Stable in wide pH range (2–12) and tolerant to organic solvents, making it a universal platform for diverse catalytic and adsorption processes.

Request Samples & Custom Formulations

Contact our technical team for tailored pore architectures, particle sizes, or surface chemistry modifications.

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